X-ray transient absorption and picosecond IR spectroscopy of fulvalene(tetracarbonyl)diruthenium on photoexcitation.
نویسندگان
چکیده
Caught in the light: The fulvalene diruthenium complex shown on the left side of the picture captures sun light, causing initial Ru-Ru bond rupture to furnish a long-lived triplet biradical of syn configuration. This species requires thermal activation to reach a crossing point (middle) into the singlet manifold on route to its thermal storage isomer on the right through the anti biradical.
منابع مشابه
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عنوان ژورنال:
- Angewandte Chemie
دوره 51 31 شماره
صفحات -
تاریخ انتشار 2012